By Karl A D Swift
This e-book is a compilation of 16 of the twenty papers provided on the 2001 RSC/SCI flavours and fragrances convention at Scarman condominium, collage of Warwick.
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Extra resources for Advances in Flavours and Fragrances: From the Sensation to the Synthesis
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S . Cain, Fundamental and Applied Toxicology, 1996,31,7 1. F. Yoshii and S . Hirono, Chem. Senses, 1996,21,201. M. Akamatsu, K. Nishimura, H. Osabe, T. Ueno and T. Fujita, Pestic Biochem. , 1994, 48, 15. G. Buchbaur, A. Hillisch, K. Mraz and P. Wolshann, Helv. Chim. , 1994,77, 2286. A. J. Calder, A. J. Wyatt, A. D. Frenkel and E. J. Casida, J. Computer-Aided Mol. Design, 1993,7,45. D. R. Cramer 111, D. J. Bunce, E. D. Patterson and E. I. Franck, Quunt. -Act. , 1988,7, 18. H. K. Engel, A. R. Flath, G .
T, L 10 r - 20 ,. 30 eL- N4 r . p - - - 40 1 h cln T r,- ,-,---:-r-i7-'T1 j 7c En r' l3rm) -00 -00 I -;w , , -'lo - * 7 i;O - ~ l T :30 r - ~ r ~ +l;o -- Figure 13 Heteronuclear correlated 2 0 NMR spectrum (HMBC) of 2-methyl-5-propoxyor 2 -methy 1-6-propoxypyrazine Analytical 47 Figures 14 to 19 show the range of 15Nchemical shifts that can be expected for various functional groups. Figure 20 details proton, carbon, and nitrogen shifts for several wellknown pyrazines. The effect of substitution on the NMR of pyrazines is detailed in figures 21 and 22.